By H. P. Bonzel, R. Denecke, W. Eck, A. Föhlisch, G. Held, W. Jaegermann, N. Martensson, T. Mayer, H. Over, H. P. Steinrück
Surface technology is known as a comparatively younger clinical self-discipline, involved in the actual and chemical houses of phenomena on fresh and coated stable surfaces, studied less than numerous stipulations. The adsorption of atoms and molecules on good surfaces is, for instance, this type of , attached with roughly drastic adjustments of all floor houses. An adsorption occasion is often saw in nature and located to be of technical significance in lots of business procedures. accordingly, floor technology is interdisciplinary via its very nature, and as such an enormous middleman among basic and utilized research.
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Extra resources for Adsorbed Layers on surfaces
Substrate surface Ag(111) Cr(110) 10 L N2 Cr(111) Binding energies of core and valence states Ref. 5 eV above EF, probably due to hybridization of N(2p) with Ni(d), KRIPES: flat dispersion. 3 eV, no dispersion perp. to Rh-N rows. 8 eV (on-surface) 97F1/XPS N(2p) 6 eV below EF 79S1/UPS low N coverage low N coverage c(2×2)N c(2×2)N c(2×2)N Ni(100) (2×2)N (2×2)p4g-N 1 - 1000 L 1 - 1000L W(110) (2×2)N 90N1/XPS 94W1/UPS 94W1/SXES 90N1/XPS 89K1/UPS 97F1/XPS 97F1/XPS Landolt-Börnstein New Series III/42A4 Ref.
5 K/s) 98K1/MC 60B1 85S2 60B1 60B1 75E1/TDS 75B3/ID 75B3/ID 76B3/TDS 76B3/TDS 75B3/ID 66B1 88C1 Remark: Adsorption micro calorimetry in surface science studies: The reader can find calorimetrically measured molar heats of adsorption of gaseous adsorbates on wires and ribbons, which are not included in this table [96C2]. 2 Adsorption of C, N, and O on metal surfaces [Ref. p. 3 Oxygen-metal bond strength (ab initio calculations) Table 3. The O-metal bond strength as computed by ab-initio calculations.
55 substrate structure Me-O stretch vibration [meV] adsorption site Ref. Pt(111) (2×2)1O (2×2)3O “oxide” low cov. 58 (perp. 4 95 70 89P1, 82S3 89P1 80G1 97W2, 98F1 low cov. 5, 49 60 (theory) oxide on-top octahedral 93A1 Landolt-Börnstein New Series III/42A4 Ref. p. 6 Local atomic oxygen-metal geometry Table 6. The O-metal bond length and other structural characteristics. 07 MR reconstruction analog to Cu(110)-c(6×2) every 2nd row missing subsurface induced reconstruction. 80 fcc assumed 3-fold coordinated.